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李永舫

李永舫

院士 太阳能电池 电极材料

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个人简介

  李永舫,男,1948年8月10日生于重庆,籍贯河南睢县。博士,高分子化学、物理化学专家,中国科学院院士。中国科学院化学研究所有机固体重点实验室研究员,苏州大学材料与化学化工学部特聘教授。 教育简历   1966届高中,1977级大学(华东化工学院现华东理工大学抗菌素专业)。   1982年在华东化工学院(现华东理工大学)化学系获硕士学位(专业:物理化学;研究方向:化学热力学和物质结构)。   1986年在复旦大学化学系获博士学位(专业:物理化学;研究方向:电极过程动力学;导师:吴浩青院士)。 工作简历   1986-1988中科院化学所博士后(专业:高分子物理化学;研究方向:导电聚合物电化学;合作导师:钱人元院士)   1988年博士后出站后留化学所工作,1993年晋升研究员,1996年被评为博士生导师。曾于1988年10月至1991年4月、1992年10月至1993年元月、1994年元月至  1994年4月到日本文部省分子科学研究所井口洋夫教授(日本学士院院士、中国科学院外籍院士)实验室进行访问研究;   1997年6月至1998年6月到美国University of California at Santa Barbara(UCSB)Alan J. Heeger教授(2000年诺贝尔化学奖获得者、美国科学院院士、中国科学院外籍院士)实验室进行访问研究;   1998年10月至11月到日本分子科学研究所日本学术振兴会(JSPS)访问教授;   2000年2月至5月到美国University of California at Los Angeles (UCLA) Yang Yang教授实验室高访(国家留学基金资助)。 研究兴趣   (1)聚合物太阳能电池光伏材料,包括共轭聚合物给体和受体光伏材料,新型富勒烯衍生物受体光伏材料,可溶液加工有机分子光伏材料等。   (2)无机半导体纳米晶的制备及其在聚合物太阳能电池和电致发光中的应用。   (3)导电聚合物电化学和导电聚合物透明电极材料。 成果与奖励   1987年,“锂电池电极反应机理――电化学嵌入反应的研究”获国家教委科技进步二等奖(排名第二,排名第一为吴浩青院士);   1993年,“导电聚吡咯的研究”获中国科学院自然科学一等奖(排名第二,排名第一为钱人元院士);   1994年获中国科学院有突出贡献的中青年专家称号;   1995年,“导电聚吡咯的研究”获国家自然科学二等奖(排名第二,排名第一为钱人元院士);   1998年被人事部授予“中青年有突出贡献专家”称号;   2000年获中国科学院“华为”奖教金;   2005年,“导电聚合物电化学和聚合物发光电化学池的研究”获北京市科学技术奖一等奖(排名第一);   2012年获美国化学会(ACS)高分子学术报告奖(2012 Macro Lecture Award);   2013年入选汤森路透评选的2012年度Hottest Scientific Researchers. (在21位入选者中排名并列第二);   2013年当选为中国科学院院士。   迄今已发表研究SCI论文400多篇(其中影响因子5以上杂志上发表论文100多篇),刊物包括Nature Photonics、Acc.Chem. Res.、Chem. Soc. Rev.、J. Am. Chem. Soc.、ACS Nano、Angew. Chem. Int. Ed、Adv. Mater、Adv. Energy Mater.、Adv. Funct. Mater、Energy Environ. Sci.、Chem. Mater、Chem. Commun.、Macromolecules、J. Mater.Chem.、.Polym. Chem 等。与吴浩青先生合著《电化学动力学》,另在10多部著作中写有与共轭聚合物光电子材料和器件相关的部分章节。发表论文已被SCI他人引用11500余次,h-因子58。 代表性论文   (1)在聚合物太阳能电池光伏材料方面:   1. Jianhui Hou, Zhan’ao Tan, Yong Yan, Youjun He, Chunhe Yang, Yongfang Li*, “Synthesis and photovoltaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene) side chains”, J. Am. Chem. Soc.,2006, 128, 4911-4916.   2. Xiaowei Zhan*, Zhan’ao Tan, Benoit Domercq, Zesheng An, Xuan Zhang, Stephen Barlow, Yongfang Li*, Daoben Zhu*, Bernard Kippelen*, Seth R. Marder*, “A High-Mobility Electron-Transport Polymer with Broad Absorption and its use inAll-Polymer Solar Cells and Field-Effect Transistors”, J. Am. Chem. Soc., 2007, 129, 7246-7247.   3. Youjun He, Hsiang-Yu Chen, Jianhui Hou*, Yongfang Li*,”Indene-C60 bisadduct: a new acceptor for high performance polymer solar cells”, J. Am. Chem. Soc., 2010, 132,1377-1382.   4. Yen-Ju Cheng*, Chao-Hsiang Hsieh, Youjun He, Chain-Shu Hsu*, Yongfang Li*, ” Combination of indene-C60 bis-adduct and cross-linked fullerence interlayer leading to highly efficient inverted polymer solar cells”, J. Am. Chem. Soc. 2010, 132, 17381–17383.   5. Yongfang Li*, Yingping Zou, "Conjugated Polymer Photovoltaic Materials with Broad Absorption Band and High Charge Carrier Mobility", Adv.Mater., 2008, 20, 2952-2958.   6. Guangjin Zhao, Youjun He, Yongfang Li*, “6.5% Efficiency of the polymer solar cells based on poly(3-hexylthiophene) and indene-C60 bisadduct by device optimization”, Adv. Mater. , 2010, 22, 4355-4358.   7. Huixia Shang, Haijun Fan, Yao Liu, Wenping Hu*, Yongfang Li,* and Xiaowei Zhan,* “A solution processable star-shaped molecule for high performance organic solar cells”,Adv. Mater.,2011, 23, 1554–1557.   8. Maojie Zhang, Xia Guo, Yongfang Li*, “Synthesis and characterization of a copolymer based on thiazolothiazole and dithienosilole for polymer solar cells”, Adv. Energy Mater.2011, DOI: 10.1002/aenm.201100193.   9. Guangjin Zhao, Youjun He, Zheng Xu, Jianhui Hou*, Maojie Zhang, Jie Min, Hsiang-Yu Chen, Mingfu Ye, Ziruo Hong, Yang Yang*, Yongfang Li*, “Effect of carbon chain length in the substituent of PCBM-like molecules on their photovoltaic properties” , Adv. Funct. Mater.2010, 20, 1480-1487.   10. Youjun He, Guangjin Zhao, Bo Peng, Yongfang Li*,“High yield synthesis, electrochemical and photovoltaic properties of indene-C70 bisadduct”,Adv. Funct. Mater., 2010,20, 3383-3389.   11. Ye Huang, Lijun Huo, Shaoqing Zhang, Xia Guo, Charles C. Han*, Yongfang Li*, Jianhui Hou*, “Sulfonyl: a new application of electron-withdrawing substituent in highly efficient photovoltaic polymer”, Chem. Commun. 2011, DOI:10.1039/C1CC12575C.   12. Jing Zhang, Dan Deng, Chang He*, Youjun He, Maojie Zhang, Zhi-Guo Zhang, Zhanjun Zhang, Yongfang Li*, “Star-shaped molecules with triphenylamine core and dicyanovinyl end-groups for organic solar cells”, Chem. Mater., 2011, 23, 817-822.   13. Jianhui Hou, Lijun Huo, Chang He, Chunhe Yang, Yongfang Li*,“Synthesis and Absorption Spectra of Poly[3-(phenylene-vinyl) thiophene] with Conjugated Side-Chains", Macromolecules,2006, 39, 594-603.   14. Lijun Huo, Xia Guo, Shaoqing Zhang, Yongfang Li, Jianhui Hou,PBDTTTZ: A broad band gap conjugated polymer with high photovoltaic performance in polymer solar cells”, Macromolecules,2011, DOI: 10.1021/ma200743b.   (2)在无机半导体纳米晶制备和共轭聚合物、无机半导体纳米晶杂化光电子器件方面:   15. Qingjiang Sun, Y. Andrew Wang*, Lin Song Li, Daoyuan Wang, Ting Zhu, Jian Xu, Chunhe Yang and Yongfang Li*, “Bright, Multicoloured Light Emitting Diodes Based on Quantum Dots”, Nature Photonics, 2007, 1, 717-722.   16. Yunchao Li, Haizheng Zhong, Rui Li, Yi Zhou, Chunhe Yang, Yongfang Li*, “High-yield fabrication and electrochemical characterization of tetrapod-shaped CdSe, CdTe and CdSexTe1-x nanocrystals”, Adv. Funct. Mater., 2006, 16, 1705-1716.   17. Haizheng Zhong, Yi Zhou, Mingfu Ye,Xiang Wang,Youjun He, Jianping Ye, Chang He, Chunhe Yang, Yongfang Li*, “Controlled Synthesis and Optical Properties of Colloidal Ternary Chalcogenide CuInS2 Nanocrystals”, Chem. Mater.2008, 20, 6434-6443.   (3)在导电聚合物电化学和聚合物发光电化学池方面:   18. Chunhe Yang, Qingjiang Sun, Jing Qiao, Yongfang Li*, “Ionic liquid Doped Polymer Light-emitting Electrochemical Cells”, J. Phys. Chem. B, 2003, 107, 12981-12988.   19. Yongfang Li*, Yong Cao, Jun Gao, Deli Wang, Gang Yu, Alan J. Heeger, “Electrochemical properties of luminescent polymers and polymer light-emitting electrochemical cells”, Synthetic Metals, 1999, 99, 243-248.   20. Yongfang Li, Renyuan Qian, “On the nature of redox processes in the cyclic voltammetry of polypyrrole in aqueous solutions”,J. Electroanal. Chem., 1993, 362, 267-272.

研究领域

聚合物太阳能电池光伏材料和器件以及导电聚合物电化学

成果及荣誉

1987年,“锂电池电极反应机理――电化学嵌入反应的研究”获国家教委科技进步二等奖(排名第二,排名第一为吴浩青院士);
1993年,“导电聚吡咯的研究”获中国科学院自然科学一等奖(排名第二,排名第一为钱人元院士);
1994年获中国科学院有突出贡献的中青年专家称号;
1995年,“导电聚吡咯的研究”获国家自然科学二等奖(排名第二,排名第一为钱人元院士);
1998年被人事部授予“中青年有突出贡献专家”称号;
2000年获中国科学院“华为”奖教金;
2005年,“导电聚合物电化学和聚合物发光电化学池的研究”获北京市科学技术奖一等奖(排名第一);
2012年获美国化学会(ACS)高分子学术报告奖(2012 Macro Lecture Award);
2013年入选汤森路透评选的2012年度Hottest Scientific Researchers. (在21位入选者中排名并列第二);
2013年当选为中国科学院院士。
  迄今已发表研究SCI论文400多篇(其中影响因子5以上杂志上发表论文100多篇),刊物包括Nature Photonics、Acc.Chem. Res.、Chem. Soc. Rev.、J. Am. Chem. Soc.、ACS Nano、Angew. Chem. Int. Ed、Adv. Mater、Adv. Energy Mater.、Adv. Funct. Mater、Energy Environ. Sci.、Chem. Mater、Chem. Commun.、Macromolecules、J. Mater.Chem.、.Polym. Chem 等。与吴浩青先生合著《电化学动力学》,另在10多部著作中写有与共轭聚合物光电子材料和器件相关的部分章节。发表论文已被SCI他人引用11500余次,h-因子58。

承担科研项目

“锂电池电极反应机理――电化学嵌入反应的研究”;“导电聚吡咯的研究”;“导电聚合物电化学和聚合物发光电化学池的研究”

热门文献

(1)在聚合物太阳能电池光伏材料方面:
  1. Jianhui Hou, Zhan’ao Tan, Yong Yan, Youjun He, Chunhe Yang, Yongfang Li*, “Synthesis and photovoltaic properties of two-dimensional conjugated polythiophenes with bi(thienylenevinylene) side chains”, J. Am. Chem. Soc.,2006, 128, 4911-4916.
  2. Xiaowei Zhan*, Zhan’ao Tan, Benoit Domercq, Zesheng An, Xuan Zhang, Stephen Barlow, Yongfang Li*, Daoben Zhu*, Bernard Kippelen*, Seth R. Marder*, “A High-Mobility Electron-Transport Polymer with Broad Absorption and its use inAll-Polymer Solar Cells and Field-Effect Transistors”, J. Am. Chem. Soc., 2007, 129, 7246-7247.
  3. Youjun He, Hsiang-Yu Chen, Jianhui Hou*, Yongfang Li*,”Indene-C60 bisadduct: a new acceptor for high performance polymer solar cells”, J. Am. Chem. Soc., 2010, 132,1377-1382.
  4. Yen-Ju Cheng*, Chao-Hsiang Hsieh, Youjun He, Chain-Shu Hsu*, Yongfang Li*, ” Combination of indene-C60 bis-adduct and cross-linked fullerence interlayer leading to highly efficient inverted polymer solar cells”, J. Am. Chem. Soc. 2010, 132, 17381–17383.
  5. Yongfang Li*, Yingping Zou, "Conjugated Polymer Photovoltaic Materials with Broad Absorption Band and High Charge Carrier Mobility", Adv.Mater., 2008, 20, 2952-2958.
  6. Guangjin Zhao, Youjun He, Yongfang Li*, “6.5% Efficiency of the polymer solar cells based on poly(3-hexylthiophene) and indene-C60 bisadduct by device optimization”, Adv. Mater. , 2010, 22, 4355-4358.
  7. Huixia Shang, Haijun Fan, Yao Liu, Wenping Hu*, Yongfang Li,* and Xiaowei Zhan,* “A solution processable star-shaped molecule for high performance organic solar cells”,Adv. Mater.,2011, 23, 1554–1557.
  8. Maojie Zhang, Xia Guo, Yongfang Li*, “Synthesis and characterization of a copolymer based on thiazolothiazole and dithienosilole for polymer solar cells”, Adv. Energy Mater.2011, DOI: 10.1002/aenm.201100193.
  9. Guangjin Zhao, Youjun He, Zheng Xu, Jianhui Hou*, Maojie Zhang, Jie Min, Hsiang-Yu Chen, Mingfu Ye, Ziruo Hong, Yang Yang*, Yongfang Li*, “Effect of carbon chain length in the substituent of PCBM-like molecules on their photovoltaic properties” , Adv. Funct. Mater.2010, 20, 1480-1487.
  10. Youjun He, Guangjin Zhao, Bo Peng, Yongfang Li*,“High yield synthesis, electrochemical and photovoltaic properties of indene-C70 bisadduct”,Adv. Funct. Mater., 2010,20, 3383-3389.
  11. Ye Huang, Lijun Huo, Shaoqing Zhang, Xia Guo, Charles C. Han*, Yongfang Li*, Jianhui Hou*, “Sulfonyl: a new application of electron-withdrawing substituent in highly efficient photovoltaic polymer”, Chem. Commun. 2011, DOI:10.1039/C1CC12575C.
  12. Jing Zhang, Dan Deng, Chang He*, Youjun He, Maojie Zhang, Zhi-Guo Zhang, Zhanjun Zhang, Yongfang Li*, “Star-shaped molecules with triphenylamine core and dicyanovinyl end-groups for organic solar cells”, Chem. Mater., 2011, 23, 817-822.
  13. Jianhui Hou, Lijun Huo, Chang He, Chunhe Yang, Yongfang Li*,“Synthesis and Absorption Spectra of Poly[3-(phenylene-vinyl) thiophene] with Conjugated Side-Chains", Macromolecules,2006, 39, 594-603.
  14. Lijun Huo, Xia Guo, Shaoqing Zhang, Yongfang Li, Jianhui Hou,PBDTTTZ: A broad band gap conjugated polymer with high photovoltaic performance in polymer solar cells”, Macromolecules,2011, DOI: 10.1021/ma200743b.
  (2)在无机半导体纳米晶制备和共轭聚合物、无机半导体纳米晶杂化光电子器件方面:
  15. Qingjiang Sun, Y. Andrew Wang*, Lin Song Li, Daoyuan Wang, Ting Zhu, Jian Xu, Chunhe Yang and Yongfang Li*, “Bright, Multicoloured Light Emitting Diodes Based on Quantum Dots”, Nature Photonics, 2007, 1, 717-722.
  16. Yunchao Li, Haizheng Zhong, Rui Li, Yi Zhou, Chunhe Yang, Yongfang Li*, “High-yield fabrication and electrochemical characterization of tetrapod-shaped CdSe, CdTe and CdSexTe1-x nanocrystals”, Adv. Funct. Mater., 2006, 16, 1705-1716.
  17. Haizheng Zhong, Yi Zhou, Mingfu Ye,Xiang Wang,Youjun He, Jianping Ye, Chang He, Chunhe Yang, Yongfang Li*, “Controlled Synthesis and Optical Properties of Colloidal Ternary Chalcogenide CuInS2 Nanocrystals”, Chem. Mater.2008, 20, 6434-6443.
  (3)在导电聚合物电化学和聚合物发光电化学池方面:
  18. Chunhe Yang, Qingjiang Sun, Jing Qiao, Yongfang Li*, “Ionic liquid Doped Polymer Light-emitting Electrochemical Cells”, J. Phys. Chem. B, 2003, 107, 12981-12988.
  19. Yongfang Li*, Yong Cao, Jun Gao, Deli Wang, Gang Yu, Alan J. Heeger, “Electrochemical properties of luminescent polymers and polymer light-emitting electrochemical cells”, Synthetic Metals, 1999, 99, 243-248.
  20. Yongfang Li, Renyuan Qian, “On the nature of redox processes in the cyclic voltammetry of polypyrrole in aqueous solutions”,J. Electroanal. Chem., 1993, 362, 267-272.

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